Photodissociation (also called photolysis or photodecomposition) is a chemical reaction using the energy of an incoming photon to break a chemical bond, i.e., to dissociate two parts of the molecule. The higher the energy, the more likely the photon has the energy to carry out the dissociation, thus many types involve gamma rays, X-rays or ultraviolet rays.
A photodissociation region (or photon-dominated region or PDR) is an interstellar gas cloud in which ultraviolet photons dissociate the expected compounds. Such regions occur in at the border between molecular clouds and HII regions, in the region where far ultraviolet can penetrate.
Nuclear photodissociation is an unrelated nuclear reaction, essentially, fission triggered by a photon rather than by (for example) an incoming proton. It can occur in some stellar processes and events.